Thanks Jim and Sfcu for the tips and assistance. Rooster went above and beyond and he found some instructions online (none came with the solenoid). I connected it to a 12v 0.5a wall wart correctly, and the solenoid worked, heard the click, the led light came on, but the valves did not move. It is a pneumatic solenoid. Took it apart and saw the magnet move with the current, but still couldn't get the valve to move. There were some other reviews that commented on this, and one said that it needed positive pressure to work, not negative pressure. Either way, I blew and sucked on that sucker until I turned blue and I couldn't get it to work, but I think it was a pneumatic error, not electrical.
So I just went ahead and bought the one on the BRS FAQ vid. At least I know I can get it to work, even though it is a 2 way valve instead of a 3 way. No point in keeping my pH above 8.3, using up the canister.