I agree with ET, test the locline. I think your 'one draws air' logic is correct but test it! With one higher than the others, turn the power off and see what happens. If it works and you can configure one to never be pushed lower, that will solve the drain back question.
To prevent the skimmer from overflowing when the main pump is off include these lines of code in the skimmer outlet -
If Outlet R_pump = OFF Then OFF
Defer 005:00 Then ON
The first line cuts off the skimmer if the return pump (R_pump) is off. The second line makes the skimmer outlet wait five minutes before turning on, allowing the sump to get back to normal level after a power outage or intentional shut down.
As to placement of all the extras...
It's always a good idea to have the RO/DI close to a water source. I put salt mix close to RO/DI. It's easy to pump water from either to the tank. I have my mix station outside and pump SW 50 feet to the tank for water changes.
I'd keep all the probes in the sump area. Wires running over the top of the tank will get damaged.
It would help if you could post pictures of the areas so we can visualize it better. The LL pic is nice but could you post slightly larger ones for us old guys?
