Carbonic acid is partly why the pH is so low. The other reason is that RODI is very pure and most pH meters and tests don't work well for very pure water. Carbonic acid will dissipate with time. I no longer use RODI less than 48 hours unless I really need it. As Jim says, adding a powerhead will reduce the carbonic acid. Don't use an airpump though (I forget the reason cited).