Yes, SunPower have the most efficient panels. Although, make some price calculations to see if they are really worth it - if you have the space it might be more cost effective to add more panels than buying a smaller number of the SunPower panels for same total output.
In my case, the roof could take at most 14 panels, and even those on different sides, so I wanted to go with SunPower for maximizing the output. Then SunPower said that their panels cannot work with micro inverters and they themselves said that can't do the job, they require at least 4 panels facing the same direction and 3 panels on the same roof facade. In the end I went with a set of higher efficiency LG panels (LG315 if I remember correctly) + micro inverters through a smaller solar installer. I'm happy so far, my PG&E bill dropped from $150 to around $20 in the summer and $40 in the winter. I'm down in low side of tier 2 now.